Let $W$ be a Weyl group, $\Sigma$ a set of simple reflections in $W$ related to a basis $\Delta$ for the root system $\Phi$ associated with $W$ and $\theta$ an involution such that $\theta(\Delta) = \Delta$. We show that the set of $\theta$-twisted involutions in $W$, $\mathcal{I}_{\theta} = \{w\in W \mid \theta(w) = w^{-1}\}$ is in one to one correspondence with the set of regular involutions $\mathcal{I}_{\operatorname{Id}}$. The elements of $\mathcal{I}_{\theta}$ are characterized by sequences in $\Sigma$ which induce an ordering called the Richardson-Springer Poset. In particular, for $\Phi$ irreducible, the ascending Richardson-Springer Poset of $\mathcal{I}_{\theta}$, for nontrivial $\theta$ is identical to the descending Richardson-Springer Poset of $\mathcal{I}_{\operatorname{Id}}$.

We generalize the well-known result that a square traceless complex matrix is unitarily similar to a matrix with zero diagonal to arbitrary connected semisimple complex Lie groups $G$ and their Lie algebras $\mathfrak{g}$ under the action of a maximal compact subgroup $K$ of $G$. We also introduce a natural partial order on $\mathfrak{g}$: $x\le y$ if $f(K\cdot x) \subseteq f(K\cdot y)$ for all $f\in \mathfrak{g}^*$, the complex dual of $\mathfrak{g}$. This partial order is $K$-invariant and induces a partial order on the orbit space $\mathfrak{g}/K$. We prove that, under some restrictions on $\mathfrak{g}$, the set $f(K\cdot x)$ is star-shaped with respect to the origin.